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鲁敏, 熊祖鸿, 房科靖, 李继青, 黎涛. 粉煤灰基催化材料的研究进展[J]. 环境化学, 2019, 38(2): 297-305. doi: 10.7524/j.issn.0254-6108.2018040907
引用本文: 鲁敏, 熊祖鸿, 房科靖, 李继青, 黎涛. 粉煤灰基催化材料的研究进展[J]. 环境化学, 2019, 38(2): 297-305. doi: 10.7524/j.issn.0254-6108.2018040907
shu
LU Min, XIONG Zuhong, FANG Kejing, LI Jiqing, LI Tao. Coal fly ash based catalytic materials: A review[J]. Environmental Chemistry, 2019, 38(2): 297-305. doi: 10.7524/j.issn.0254-6108.2018040907
Citation: LU Min, XIONG Zuhong, FANG Kejing, LI Jiqing, LI Tao. Coal fly ash based catalytic materials: A review[J]. Environmental Chemistry, 2019, 38(2): 297-305. doi: 10.7524/j.issn.0254-6108.2018040907
shu

粉煤灰基催化材料的研究进展

  • 1.

    中国科学院广州能源研究所, 广州, 510640;

  • 2.

    中国科学院可再生能源重点实验室, 广州, 510640;

  • 3.

    广东省新能源和可再生能源研究开发与应用重点实验室, 广州, 510640

  • 基金项目:

    国家自然科学基金（21606228）资助

Coal fly ash based catalytic materials: A review

  • 1.

    Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou, 510640, China;

  • 2.

    Chinese Academy of Sciences key Laboratory of Renewable Energy, Guangzhou, 510640, China;

  • 3.

    Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou, 510640, China

  • Fund Project: Supported by the National Natural Science Foundation of China (21606228)

  • 摘要: 粉煤灰应用于催化材料的制备是实现其高附加值利用的重要途径，本文详细阐述了粉煤灰的化学组成与结构特性，综述了粉煤灰基催化剂在有机物降解、有机合成和催化制氢等领域的研究进展，讨论了粉煤灰在不同催化反应过程中的作用原理.粉煤灰作为一种富含Si、Al的复合载体，具有单一载体不可替代的优势，其组成与结构的改变对催化剂的性能有很大的影响，不同的活性组分与结构对应不同的反应类型，具有非常广泛的适应性.影响催化剂性能的主要因素包括：粉煤灰中Si—O—Si或Al—O—Si结构的重组，Fe、Ca、Na、K等元素对催化剂的修饰，活性组分与粉煤灰载体之间的相互作用等.由此可知，准确调控粉煤灰的化学组成与结构是提高粉煤灰基催化剂性能的重要手段，也是未来拓展粉煤灰高附加值利用空间的理论依据.
    Abstract: Application of coal fly ash as catalytic materials is an important means to realize its high added-value utilization. In this paper, the chemical composition and structure characteristics of coal fly ash were described in detail. The research status of coal fly ash based catalysts applied in organic pollatant degradation, organic synthesis and catalytic hydrogen production was reviewed, and the action mechanism of coal fly ash in different catalytic reactions were discussed. Coal fly ash, as a composite carrier, is rich in Si and Al, and has some irreplaceable advantages over single carriers. The composition and structure of coal fly ash had great influence on catalytic performance, and different active components and structure corresponded to different reactions. So, it had a wide range of adaptability. The main factors influencing catalyst performance include structure reorganization of Si-O-Si or Al-O-Si in coal fly ash, catalysts modification by Fe, Ca, Na, K, the interaction between the active components and the coal fly ash carrier, etc. Therefore, regulating the chemical composition and structure of coal fly ash accurately is an important means to improve the performance of coal fly ash based catalysts and the theoretical basis for expanding the high value-added utilization of coal fly ash in the future.
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出版历程
  • 收稿日期:  2018-04-09
  • 刊出日期:  2019-02-15
鲁敏, 熊祖鸿, 房科靖, 李继青, 黎涛. 粉煤灰基催化材料的研究进展[J]. 环境化学, 2019, 38(2): 297-305. doi: 10.7524/j.issn.0254-6108.2018040907
引用本文: 鲁敏, 熊祖鸿, 房科靖, 李继青, 黎涛. 粉煤灰基催化材料的研究进展[J]. 环境化学, 2019, 38(2): 297-305. doi: 10.7524/j.issn.0254-6108.2018040907
shu
LU Min, XIONG Zuhong, FANG Kejing, LI Jiqing, LI Tao. Coal fly ash based catalytic materials: A review[J]. Environmental Chemistry, 2019, 38(2): 297-305. doi: 10.7524/j.issn.0254-6108.2018040907
Citation: LU Min, XIONG Zuhong, FANG Kejing, LI Jiqing, LI Tao. Coal fly ash based catalytic materials: A review[J]. Environmental Chemistry, 2019, 38(2): 297-305. doi: 10.7524/j.issn.0254-6108.2018040907
shu

粉煤灰基催化材料的研究进展

  • 1.  中国科学院广州能源研究所, 广州, 510640;
  • 2.  中国科学院可再生能源重点实验室, 广州, 510640;
  • 3.  广东省新能源和可再生能源研究开发与应用重点实验室, 广州, 510640
  • 收稿日期:  2018-04-09
基金项目:

国家自然科学基金（21606228）资助

摘要: 粉煤灰应用于催化材料的制备是实现其高附加值利用的重要途径，本文详细阐述了粉煤灰的化学组成与结构特性，综述了粉煤灰基催化剂在有机物降解、有机合成和催化制氢等领域的研究进展，讨论了粉煤灰在不同催化反应过程中的作用原理.粉煤灰作为一种富含Si、Al的复合载体，具有单一载体不可替代的优势，其组成与结构的改变对催化剂的性能有很大的影响，不同的活性组分与结构对应不同的反应类型，具有非常广泛的适应性.影响催化剂性能的主要因素包括：粉煤灰中Si—O—Si或Al—O—Si结构的重组，Fe、Ca、Na、K等元素对催化剂的修饰，活性组分与粉煤灰载体之间的相互作用等.由此可知，准确调控粉煤灰的化学组成与结构是提高粉煤灰基催化剂性能的重要手段，也是未来拓展粉煤灰高附加值利用空间的理论依据.

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