2015 Volume 9 Issue 6
Article Contents

Guo Jingsong, Lin Jiaqi, Liu Liang, Chen Youpeng, Fang Fang. Removal of endocrine disrupting chemicals from aqueous solution by adsorption using modified ceramicites[J]. Chinese Journal of Environmental Engineering, 2015, 9(6): 2547-2554. doi: 10.12030/j.cjee.20150603
Citation: Guo Jingsong, Lin Jiaqi, Liu Liang, Chen Youpeng, Fang Fang. Removal of endocrine disrupting chemicals from aqueous solution by adsorption using modified ceramicites[J]. Chinese Journal of Environmental Engineering, 2015, 9(6): 2547-2554. doi: 10.12030/j.cjee.20150603

Removal of endocrine disrupting chemicals from aqueous solution by adsorption using modified ceramicites

  • Received Date: 03/07/2014
    Accepted Date: 16/04/2014
    Available Online: 09/06/2015
    Fund Project:
  • Modified ceramicites were prepared by hexadecyl trimethyl ammonium bromide (CTMAB). Experiments were carried out to evaluate the adsorption equilibrium and kinetics of endocrine disrupt chemicals (EDCs) (metoprolol, sulfamethoxazole, carbamazepine, clofibric acid, 17α-ethynylestradiol) onto original and modified ceramicites. Results showed that the CTMAB treatment changed the pore structure and surface functional groups of ceramicites: the ratio of pores that can effectively remove EDCs was strengthened, so as to the polarity of filter surface. Under room temperature, with both the initial concentration of EDCs and concentration of absorbents at 1 mg/L, the time of reaching adsorption equilibrium of EDCs onto original and modified ceramicites was about 5 minutes. The competitive adsorption of 5 EDCs on original and modified ceramicites was also investigated, concluded that SMZ and MTP were more competitive than CA. On modified ceramicites, the adsorption of EDCs was significantly improved. The adsorption process is mainly caused by both physical surface adsorption and partition. The study was conducted to provide theoretical basis of treatment of trace contaminants onto modified ceramicites, and to guarantee the drinking water treatment reaching the standard.
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  • [1] Benotti M. J., Trenholm R. A., Vanderford B. J., et al. Pharmaceuticals and endocrine disrupting compounds in U.S. drinking water. Environmental Science & Technology, 2009, 43(3): 597-603

    Google Scholar Pub Med

    [2] Yoon Y., Ryu J., Oh J., et al. Occurrence of endocrine disrupting compounds, pharmaceuticals, and personal care products in the Han River (Seoul, South Korea). Science of the Total Environment, 2010, 408(3): 636-643

    Google Scholar Pub Med

    [3] Daughton C. G. Non-regulated water contaminants: Emerging research. Environmental Impact Assessment Review, 2004, 24(7-8): 711-732

    Google Scholar Pub Med

    [4] Kolpin D. W., Furlong E. T., Meyer M. T., et al. Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000: A national reconnaissance survey. Environmental Science & Technology, 2002, 36(6): 1202-1211

    Google Scholar Pub Med

    [5] Richardson S. D. Water analysis: Emerging contaminants and current issues. Analytical Chemistry, 2007, 79(12): 4295-4324

    Google Scholar Pub Med

    [6] Padhye L. P., Yao Hong, Kung'u F. T., et al. Year-long evaluation on the occurrence and fate of pharmaceuticals, personal care products, and endocrine disrupting chemicals in an urban drinking water treatment plant. Water Research, 2014, 51: 266-276

    Google Scholar Pub Med

    [7] Comerton A. M., Andrews R. C., Bagley D. M. Practical overview of analytical methods for endocrine-disrupting compounds, pharmaceuticals and personal care products in water and wastewater. Philosophical Transactions of the Royal Society A, 2009, 367(1904): 3923-3939

    Google Scholar Pub Med

    [8] FDA, Food and Drug Administration. Approved Drug Products with Therapeutic Equivalence Evaluations. Rockville, MD: Center for Drug Evaluation and Research, 2013

    Google Scholar Pub Med

    [9] Zwiener C. Occurrence and analysis of pharmaceuticals and their transformation products in drinking water treatment. Analytical and Bioanalytical Chemistry, 2007, 387(4): 1159-1162

    Google Scholar Pub Med

    [10] Basile T., Petrella A., Boghetich G., et al. Review of endocrine-disrupting-compound removal technologies in water and wastewater treatment plants: An EU perspectives. Industrial & Engineering Chemistry Research, 2011, 50(14): 8389-8401

    Google Scholar Pub Med

    [11] Hu Zunfang, Si Xiurong, Zhang Zheyun, et al. Enhanced EDCs removal by membrane fouling during the UF process. Desalination, 2014, 336: 18-23

    Google Scholar Pub Med

    [12] Kumar A. K., Mohan S. V. Removal of natural and synthetic endocrine disrupting estrogens by multi-walled carbon nanotubes (MWCNT) as adsorbent: Kinetic and mechanistic evaluation. Separation and Purification Technology, 2012, 87: 22-30

    Google Scholar Pub Med

    [13] Cai Nan, Larese-Casanova P. Sorption of carbamazepine by commercial grapheme oxides: A comparative study with granular activated carbon and multiwalled carbon nanotubes. Journal of Colloid and Interface Science, 2014, 426: 152-161

    Google Scholar Pub Med

    [14] 阚涛涛, 蒋晓慧, 杨美, 等. CTMAB-膨润土的制备及对甲基橙的吸附. 西华师范大学学报 (自然科学版), 2010, 31(4): 372-377 Kan Taotao, Jiang Xiaohui, Yang Mei, et al. Preparation of CTMAB-bentonite and its adsorption for methyl orange. Journal of China West Normal University (Natural Sciences), 2010, 31(4): 372-377(in Chinese)

    Google Scholar Pub Med

    [15] 陈宝梁, 朱利中, 陶澍. 非离子表面活性剂对菲在水/土壤界面间吸附行为的影响. 环境科学学报, 2003, 23(1): 1-5 Chen Baoliang, Zhu Lizhong, Tao Shu. Effect of nonionic surfactant on sorption behavior of phenanthrene on interface between soil and water. Acta Scientiae Circunstantiae, 2003, 23(1): 1-5(in Chinese)

    Google Scholar Pub Med

    [16] 李冬冬, 梁达文, 唐嫣葵, 等. 表面活性剂协同膨润土处理染料废水的研究. 环境科学与技术, 2009, 32(1): 158-161 Li Dongdong, Liang Dawen, Tang Yankui, et al. Integrative disposal of dye from wastewater by mixture of surfactant and bentonite. Environmental Science & Technology, 2009, 32(1): 158-161(in Chinese)

    Google Scholar Pub Med

    [17] 陈琳. 苯胺基乙腈车间生产废水预处理工艺研究. 重庆: 重庆大学硕士学位论文, 2008 Chen Lin. Study on pre-treatment of N-phenylglycinonitrile production wastewater. Chongqing: Master Dissertation of Chongqing University, 2008(in Chinese)

    Google Scholar Pub Med

    [18] 邓朝霞. 蒙脱土有机化改性的研究进展. 广东第二师范学院学报, 2012, 32(5): 57-63 Deng Zhaoxia. Recent progress in organic modification of montmorillonite. Journal of Guangdong University of Education, 2012, 32(5): 57-63(in Chinese)

    Google Scholar Pub Med

    [19] 吴建军, 徐仁扣, 肖双成, 等. 阳离子表面活性剂用量对改性沸石吸附铬酸根的影响. 生态与农村环境学报, 2007, 23(3): 82-85 Wu Jianjun, Xu Renkou, Xiao Shuangcheng, et al. Effects of surfactant modifying zeolite on adsorption of chromate. Journal of Ecology and Rural Environment, 2007, 23(3): 82-85(in Chinese)

    Google Scholar Pub Med

    [20] Ho Y. S, McKay G. Pseudo-second order model for sorption processes. Process Biochemistry, 1999, 34(5): 451-465

    Google Scholar Pub Med

    [21] Özacar M.,Şengil I. A. A kinetic study of metal complex dye sorption onto pine sawdust. Process Biochemistry, 2005, 40(2): 565-572

    Google Scholar Pub Med

    [22] Yang Xiaoyan, Al-Duri B. Kinetic modeling of liquid-phase adsorption of reactive dyes on activated carbon. Journal of Colloid and Interface Science, 2005, 287(1): 25-34

    Google Scholar Pub Med

    [23] 童锡臻, 石宝友, 解岳, 等. 改性活性炭对水中PFOS的吸附去除研究. 环境科学, 2012, 33(9): 3132-3138 Tong Xizhen, Shi Baoyou, Xie Yue, et al. Adsorption of perfluorooctanesulfonate (PFOS) onto modified activated carbons. Environmental Science, 2012, 33(9): 3132-3138(in Chinese)

    Google Scholar Pub Med

    [24] Xia Guoshou, Pignatello J. J. Detailed sorption isotherms of polar and apolar compounds in a high-organic soil. Environmental Science & Technology, 2001, 35(1): 84-94

    Google Scholar Pub Med

    [25] Martinez C. R., Iverson B. L. Rethinking the term "pi-stacking". Chemical Science, 2012, 3(7): 2191-2201

    Google Scholar Pub Med

    [26] Chang Minyun, Juang R. S. Adsorption of tannic acid, humic acid, and dyes from water using the composite of chitosan and activated clay. Journal of Colloid and Interface Science, 2004, 278(1): 18-25

    Google Scholar Pub Med

    [27] Ji Liangliang, Liu Fengling, Xu Zhaoyi, et al. Adsorption of pharmaceutical antibiotics on template-synthesized ordered micro-and mesoporous carbons. Environmental Science & Technolgy, 2010, 44(8): 3116-3122

    Google Scholar Pub Med

    [28] 解建坤, 岳钦艳, 于慧, 等. 污泥活性炭对活性艳红K-2BP染料的吸附特性研究. 山东大学学报 (理学版), 2007, 42(3): 64-70 Xie Jiankun, Yue Qinyan, Yu Hui, et al. Adsorption properties of sludge activated carbon to brilliant red K-2BP. Journal of Shandong University (Natural Science), 2007, 42(3): 64-70

    Google Scholar Pub Med

    [29] Jung C., Park J., Lim K. H., et al. Adsorption of selected endocrine disrupting compounds and pharmaceuticals on activated biochars. Journal of Hazardous Materials, 2013, 263: 702-710

    Google Scholar Pub Med

    [30] Cho H. H., Smith B. A., Wnuk J. D., et al. Influence of surface oxides on the adsorption of naphthalene onto multi-walled carbon nanotubes. Environmental Science & Technolgy, 2008, 42(8): 2899-2905

    Google Scholar Pub Med

    [31] Chen Wei, Duan Lin, Wang Lilin, et al. Adsorption of hydroxyl-and amino-substituted aromatics to carbon nanotubes. Environmental Science & Technolgy, 2008, 42(18): 6862-6868

    Google Scholar Pub Med

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Removal of endocrine disrupting chemicals from aqueous solution by adsorption using modified ceramicites

Fund Project:

Abstract: Modified ceramicites were prepared by hexadecyl trimethyl ammonium bromide (CTMAB). Experiments were carried out to evaluate the adsorption equilibrium and kinetics of endocrine disrupt chemicals (EDCs) (metoprolol, sulfamethoxazole, carbamazepine, clofibric acid, 17α-ethynylestradiol) onto original and modified ceramicites. Results showed that the CTMAB treatment changed the pore structure and surface functional groups of ceramicites: the ratio of pores that can effectively remove EDCs was strengthened, so as to the polarity of filter surface. Under room temperature, with both the initial concentration of EDCs and concentration of absorbents at 1 mg/L, the time of reaching adsorption equilibrium of EDCs onto original and modified ceramicites was about 5 minutes. The competitive adsorption of 5 EDCs on original and modified ceramicites was also investigated, concluded that SMZ and MTP were more competitive than CA. On modified ceramicites, the adsorption of EDCs was significantly improved. The adsorption process is mainly caused by both physical surface adsorption and partition. The study was conducted to provide theoretical basis of treatment of trace contaminants onto modified ceramicites, and to guarantee the drinking water treatment reaching the standard.

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