Estimation of the air-soil exchange of phthalates

ZHU Yuanyuan; TIAN Jing; WU Guoping; WEI Fusheng

2012 Volume 31 Issue 10

Article Contents

Previous Article Next Article

ZHU Yuanyuan, TIAN Jing, WU Guoping, WEI Fusheng. Estimation of the air-soil exchange of phthalates[J]. Environmental Chemistry, 2012, 31(10): 1535-1541.

Citation:

ZHU Yuanyuan, TIAN Jing, WU Guoping, WEI Fusheng. Estimation of the air-soil exchange of phthalates[J]. Environmental Chemistry, 2012, 31(10): 1535-1541.

Estimation of the air-soil exchange of phthalates

1.
School of Environment, Tsinghua University, Beijing, 100084, China;
2.
China National Environmental Monitoring Center, Beijing, 100012, China;
3.
Anshan Environmental Monitoring Center, Anshan, 114004, China

Received Date: 31/01/2012

Fund Project:

Abstract

Air samples from an iron and steel plant and its surrounding residential areas and background areas in northeastern China were collected. The concentrations of 15 phthalates in these samples were analyzed by GC-MS (Gas Chromatography-Mass Spectrometry) method. The air-soil exchange of phthalates were investigated by the fugacity model. The results revealed that the total concentrations of the 15 phthalates (∑PAEs) were in the range of 170—487 ng·m-3 in air. DMP(dimethyl phthalate), DEP(diethyl phthalate) and DPP (dipentyl phthalate)were found to be transferred from soil to air, with an estimated exchange flux of 93.5—117.0 g·month-1·km-2,50.2—108.2 g·month-1·km-2 and 9.4—15.5 g·month-1·km-2 respectively. DiBP(diisobutyl phthalate), DBP(dibutyl phthalate), DEHP and DINP(dinonyl phthalate) were transferred from air to soil, with an estimated exchange flux of 530.6—1395.9 g·month-1·km-2,323.8—2408.8 g·month-1·km-2,1302.7—9839.6 g·month-1·km-2 and 131.4—205.9 g·month-1·km-2 respectively.
- phthalates,
- transfer flux,
- fugacity model,
- air,
- soil

References

[1]	David R M, Moore M R, Finney D C, et al. Chronic toxicity of di-(2-ethylhexyl) phthalate in mice[J]. Toxicological Science, 2000, 58(2):377-385 Google Scholar Pub Med
[2]	Agarwal D K, Lawrence W H, Autian J. Antifertility and mutagenic effects in mice from parenteral administration of Di-2-ethylhexyl phthalate(DEHP) [J]. Toxicology and Environmental Health, 1985, 16(1):71-84 Google Scholar Pub Med
[3]	Kleinsasser N H,Weissacher H, Kastenbauer E R, el al. Altered genotoxicity on mucosal cells of head and neck cancer patients due to environmental pollutants[J]. European Archives of Otorhinolaryngology, 2000, 257(6):337-342 Google Scholar Pub Med
[4]	Kleinsasser N H, Wallner B C,Kastenbauer E R, et al. Genotoxicity of di-butyl-phthalate and di-iso-butyl-phthalate in human lymphocytes and mucosal cells[J]. Teratogenesis Carcinogenesis and Mutagensis, 2001, 21(3):189-196 Google Scholar Pub Med
[5]	时国庆、李栋、卢晓珅,等.环境内分泌干扰物质的健康影响与作用机制[J].环境化学,2011,30(1):211-223 Google Scholar Pub Med
[6]	赵文红,历曙光,蔡智鸣.酞酸酯类增塑剂毒理研究进展[J].环境与职业医学,2003,20(2):135-138 Google Scholar Pub Med
[7]	Kluwe W M, Mcconnell E E, Huff J E, et al. Carcinogenicity testing of phthalate esters and related compounds by the national toxicology program and the national cancer instititute[J]. Environmental Health Prespectives, 1982, 45:129-133 Google Scholar Pub Med
[8]	张传贵.增塑剂污染及其对人体的影响[J].生物学通报,1999,34(2):20 Google Scholar Pub Med
[9]	王西奎,孟平蕊,徐广通,等.济南市土壤中钛酸酯的分析与分布[J].环境化学,1996,15(5):427-432 Google Scholar Pub Med
[10]	崔学慧,李炳华,陈鸿汉,等.中国土壤与沉积物中邻苯二甲酸酯污染水平及其吸附研究进展[J].生态环境学报,2010,19(2):472-479 Google Scholar Pub Med
[11]	王红芬,程晗煜,洪坚平.环境中酞酸酯的污染现状及防治措施[J].环境科学与管理,2010,35(7):33-36 Google Scholar Pub Med
[12]	Staples C A, Peterson D R, Parkerton T F, et al. The environmental fate of phthalate esters: A literature review[J]. Chemosphere, 1997, 35(4): 667-749 Google Scholar Pub Med
[13]	Cadogan D F,Papez M, Poppe A C, at el. An assessment of the release, occurrence and possible effect of plasticizers in the environment[J]. Progress in Rubber and Plastics Technology, 1993, 10(1):1-19 Google Scholar Pub Med
[14]	Lewis G N. The law of physico-chemical change[J]. Proceedings of the American Academy Sciences, 1901, 37(1/15):47-69 Google Scholar Pub Med
[15]	Backe C, Cousins I T, Larsson P. PCB in soils and estimated soil-air exchange fluxes of selected PCB congeners in the south of Sweden[J]. Environmental Pollution, 2004, 128(1/2): 59-72 Google Scholar Pub Med
[16]	Cousins I T, Jones K C. Air-soil exchange of semi-volatile organic compounds (SOCs) in the UK[J]. Environmental Pollution, 1998, 102(1): 105-118 Google Scholar Pub Med
[17]	Harner T, Bidleman T F, Jantunen L M M, et al.Soil-air exchange model of persistent pesticides in the United States cotton belt[J]. Environmental Toxicology and Chemistry, 2001, 20(7): 1612-1621 Google Scholar Pub Med
[18]	Mackay D, Paterson S. Evaluating the multimedia fate of organic chemicals: a Level Ⅲ fugacity model [J]. Environmental Science and Technology, 1991, 25(3):427-436 Google Scholar Pub Med
[19]	朱媛媛,田靖,景立新,等.不同城市功能区土壤中酞酸酯污染特征[J].环境科学与技术,2012,35(5):42-46 Google Scholar Pub Med
[20]	朱媛媛.典型城市空气和土壤中酞酸酯污染特征研究.北京:清华大学硕士学位论文,2009 Google Scholar Pub Med
[21]	李静,吕永龙,王铁宇,等.苯并(a)芘的环境多介质迁移和归宿模拟[J].环境工程学报,2008,2(2):279-284 Google Scholar Pub Med

Access History

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Export Citation

PDF

XML

Article Metrics

Article views(917) PDF downloads(455) Cited by(0)

Access History

Estimation of the air-soil exchange of phthalates

Received Date: 31/01/2012

Fund Project:

Key words:

phthalates /
transfer flux /
fugacity model /
air /
soil

Abstract: Air samples from an iron and steel plant and its surrounding residential areas and background areas in northeastern China were collected. The concentrations of 15 phthalates in these samples were analyzed by GC-MS (Gas Chromatography-Mass Spectrometry) method. The air-soil exchange of phthalates were investigated by the fugacity model. The results revealed that the total concentrations of the 15 phthalates (∑PAEs) were in the range of 170—487 ng·m-3 in air. DMP(dimethyl phthalate), DEP(diethyl phthalate) and DPP (dipentyl phthalate)were found to be transferred from soil to air, with an estimated exchange flux of 93.5—117.0 g·month-1·km-2,50.2—108.2 g·month-1·km-2 and 9.4—15.5 g·month-1·km-2 respectively. DiBP(diisobutyl phthalate), DBP(dibutyl phthalate), DEHP and DINP(dinonyl phthalate) were transferred from air to soil, with an estimated exchange flux of 530.6—1395.9 g·month-1·km-2,323.8—2408.8 g·month-1·km-2,1302.7—9839.6 g·month-1·km-2 and 131.4—205.9 g·month-1·km-2 respectively.

HTML

Reference (21)

Estimation of the air-soil exchange of phthalates

Abstract

References

Access History

通讯作者: 陈斌, bchen63@163.com

Article Metrics

Access History

Estimation of the air-soil exchange of phthalates

HTML

Catalog

Export File

Citation

Format

Content