Estimation of the air-soil exchange of phthalates

ZHU Yuanyuan; TIAN Jing; WU Guoping; WEI Fusheng

2012 Volume 31 Issue 10

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ZHU Yuanyuan, TIAN Jing, WU Guoping, WEI Fusheng. Estimation of the air-soil exchange of phthalates[J]. Environmental Chemistry, 2012, 31(10): 1535-1541.

Citation:

ZHU Yuanyuan, TIAN Jing, WU Guoping, WEI Fusheng. Estimation of the air-soil exchange of phthalates[J]. Environmental Chemistry, 2012, 31(10): 1535-1541.

Estimation of the air-soil exchange of phthalates

1.
School of Environment, Tsinghua University, Beijing, 100084, China;
2.
China National Environmental Monitoring Center, Beijing, 100012, China;
3.
Anshan Environmental Monitoring Center, Anshan, 114004, China

Received Date: 31/01/2012

Fund Project:

Abstract

Air samples from an iron and steel plant and its surrounding residential areas and background areas in northeastern China were collected. The concentrations of 15 phthalates in these samples were analyzed by GC-MS (Gas Chromatography-Mass Spectrometry) method. The air-soil exchange of phthalates were investigated by the fugacity model. The results revealed that the total concentrations of the 15 phthalates (∑PAEs) were in the range of 170—487 ng·m-3 in air. DMP(dimethyl phthalate), DEP(diethyl phthalate) and DPP (dipentyl phthalate)were found to be transferred from soil to air, with an estimated exchange flux of 93.5—117.0 g·month-1·km-2,50.2—108.2 g·month-1·km-2 and 9.4—15.5 g·month-1·km-2 respectively. DiBP(diisobutyl phthalate), DBP(dibutyl phthalate), DEHP and DINP(dinonyl phthalate) were transferred from air to soil, with an estimated exchange flux of 530.6—1395.9 g·month-1·km-2,323.8—2408.8 g·month-1·km-2,1302.7—9839.6 g·month-1·km-2 and 131.4—205.9 g·month-1·km-2 respectively.
- phthalates,
- transfer flux,
- fugacity model,
- air,
- soil

References

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

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Estimation of the air-soil exchange of phthalates

Received Date: 31/01/2012

Fund Project:

Key words:

phthalates /
transfer flux /
fugacity model /
air /
soil

Abstract: Air samples from an iron and steel plant and its surrounding residential areas and background areas in northeastern China were collected. The concentrations of 15 phthalates in these samples were analyzed by GC-MS (Gas Chromatography-Mass Spectrometry) method. The air-soil exchange of phthalates were investigated by the fugacity model. The results revealed that the total concentrations of the 15 phthalates (∑PAEs) were in the range of 170—487 ng·m-3 in air. DMP(dimethyl phthalate), DEP(diethyl phthalate) and DPP (dipentyl phthalate)were found to be transferred from soil to air, with an estimated exchange flux of 93.5—117.0 g·month-1·km-2,50.2—108.2 g·month-1·km-2 and 9.4—15.5 g·month-1·km-2 respectively. DiBP(diisobutyl phthalate), DBP(dibutyl phthalate), DEHP and DINP(dinonyl phthalate) were transferred from air to soil, with an estimated exchange flux of 530.6—1395.9 g·month-1·km-2,323.8—2408.8 g·month-1·km-2,1302.7—9839.6 g·month-1·km-2 and 131.4—205.9 g·month-1·km-2 respectively.

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Estimation of the air-soil exchange of phthalates

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