贵州草海不同土地利用方式表层土壤重金属污染现状评估
Assessment of heavy metal pollution in the surface soils of different land use patterns in Caohai, Guizhou
-
摘要: 土壤重金属污染问题日益加剧,而土壤重金属来源解析及污染评价对其污染防治具有重要意义.以贵州草海沼泽地、耕地和林地表层土壤(0-20 cm)为研究对象,采用电感耦合等离子发射光谱仪(ICP-OES)和原子荧光测定仪(AFS)测定土壤中Zn、Cr、Pb、Ni、Cu、As等6种重金属元素含量,并对其进行源解析及污染现状评估.结果表明,草海整体研究区表层土壤元素含量为Zn (144.75 mg·kg-1) > Cr (93.03 mg·kg-1) > Pb (45.33 mg·kg-1) > Ni (45.08 mg·kg-1) > Cu (29.48 mg·kg-1) > As (25.19 mg·kg-1),其中Zn、Pb、Ni、As含量高于贵州背景值,分别高于背景值的45.48%、28.78%、25.97%、15.29%.元素As在耕地和林地,元素Cr、Cu、Pb在沼泽地和林地,以及元素Zn在沼泽地、耕地和林地都具有显著差异(PP>0.05).3种土地利用方式中,元素Zn、Pb、Ni、As可能主要来源于工业、农业、交通运输等人为源,而Cr、Cu来源于母岩风化、植被凋落物等自然源.土壤重金属污染评价表明,贵州草海不同土地利用方式表层土壤重金属污染处于轻微状态,未造成严重的潜在生态风险.本研究能够为贵州草海土地利用的合理规划、土壤资源保护和重金属污染防治提供数据支持.Abstract: It is of great significance to analyze the pollution sources of soil heavy metals for their prevention and controls under the situation of increasing heavy metal pollution in soils. This study focused on the surface soils (0-20 cm) of the marsh lands, cultivated lands and forest lands in Caohai, Guizhou. The concentrations of six heavy metals in soils including Zn, Cr, Pb, Ni, Cu and As, were determined by ICP-OES and AFS. Source analysis and pollution status evaluation of the heavy metals in soils were carried out. The results showed that the average concentrations of Zn, Cr, Pb, Ni, Cu and As in the surface soils, were 144.75, 93.03, 45.33, 45.08, 29.48 and 25.19 mg·kg-1, respectively. Among them, the concentrations of Zn, Pb, Ni and As were significantly higher than the soil background values of Guizhou, which were 45.48%、28.78%、25.97%、15.29%, respectively. The concentrations of As, Cr, Cu, Pb and Zn in the three land use patterns were significantly different (PP>0.05). Zn, Pb, Ni and As in the surface soils mainly derived from human sources such as industry, agriculture, and transportation. However, Cr and Cu came from natural sources such as parent rock weathering and vegetation litter. Based on the evaluation of soil heavy metal pollution, it can be seen that the surface soil heavy metal pollution in different land use patterns was mild and did not cause serious potential ecological risk in Caohai, Guizhou Province. Therefore, this study can provide a data reference for the rational planning of land use, protection of soil resources and the prevention and control of heavy metal pollution in Caohai, Guizhou.
-
[1] ABRAHAMS P W. Soils:Their implications to human health[J]. Science of the Total Environment, 2002, 292:1-32. [2] 胡国成, 张丽娟, 齐剑英, 等. 贵州万山汞矿周边土壤重金属污染特征及风险评价[J]. 生态环境学报, 2015, 24(5):879-885. HU G C, ZHANG L J, QI J Y, et al. Contaminant characteristics and risk assessment of heavy metals in soils from Wanshan mercury mine area, Guizhou Province[J]. Ecology and Environmental Sciences, 2015, 24(5):879-885(in Chinese).
[3] 周建军, 周桔, 冯仁国. 我国土壤重金属污染现状与治理战略[J]. 中国科学院院刊, 2014, 29(3):315-320 , 350. ZHOU J J, ZHOU J, FENG R G. Status of China's heavy metal contamination in soil and its remediation strategy[J]. Bulletin of Chinese Academy of Sciences, 2014, 29(3):315-320, 350(in Chinese).
[4] 张连科, 李海鹏, 黄学敏, 等. 包头某铝厂周边土壤重金属的空间分布及来源解析[J]. 环境科学, 2016, 37(3):1139-1146. ZHANG L K, LI H P, HUANG X M, Soil heavy metal spatial distribution and source analysis around an aluminum plant in Baotou[J]. Environmental Sciences, 2016, 37(3):1139-1146(in Chinese).
[5] 程先, 王瑞霖, 王建力, 等. 海河流域西部地区水库沉积物重金属潜在生态风险评价[J]. 应用生态学报, 2015, 26(5):1495-1500. CHENG X, WANG R L, WANG J L, et al. Potential ecological risks assessment of heavy metals in the reservoir sediment of the western Haihe River basin[J]. Chinese Journal of Applied Ecology, May 2015, 26(5):1495-1500(in Chinese).
[6] XIAO R, BAI J, GAOH, et al. Distribution and contamination assessment of heavy metals in water and soils from the college town in the Pearl River Delta, China[J]. Clean-Soil, Air, Water, 2012, 40:1167-1173. [7] 冯乙晴, 刘灵飞, 肖辉林, 等. 深圳市典型工业区土壤重金属污染特征及健康风险评价[J]. 生态环境学报, 2017.26(6):1051-1058. FENG Y Q, LIU L F, XIAO H L, et al. Pollution characteristics and health risk assessment of heavy metals in soil of typical industrial district of Shenzhen[J]. Ecology and Environmental Sciences, 2017, 26(6):1051-1058(in Chinese).
[8] IZQUIERDO M, DE M E, ORTEGA M F, et al. Bioaccessibility of metals and human health risk assessment in community urban gardens[J]. Chemosphere, 2015, 135:312-318. [9] 李清良, 吴倩, 高进波, 等. 基于小流域尺度的土壤重金属分布与土地利用相关性研究-以厦门市坂头水库流域为例[J]. 生态学报, 2015, 35(16):5486-5494. LI Q L, WU Q, GAO J B, et al. Distribution of heavy metals in topsoils affected by land use patterns at a small watershed scale:A case study in the Bantou Reservoir watershed in Xiamen, China[J]. Acta Ecologica Sinica, 2015, 35(16):5486-5494(in Chinese).
[10] 陈宗娟, 张倩, 张强, 等. 天津东南部某区域不同土地利用方式下土壤重金属的累积特征[J]. 生态与农村环境学报, 2015, 31(2):166-173. CHEN Z J, ZHANG Q, ZHANG Q, et al. Accumulation characteristics of heavy metals in soils as affected by land use in southeast Tianjin[J]. Journal of Ecology and Rural Environment, 2015, 31(2):166-173(in Chinese).
[11] 马剑宇, 赵佐平, 闵锁田. 不同土壤重金属污染评价方法对比研究[J]. 现代农业科技, 2016(13):223-225. MA J Y, ZHAO Z P, MIN S T. Comparative study of different soil heavy metal pollution evaluation method[J]. Modern Agricultural Sciences and Technology, 2016 (13):223-225(in Chinese).
[12] [13] 李鹏辉, 邹晓燕, 楼婕, 等. 不同季节垃圾填埋场周围重金属污染特征及评价[J]. 环境化学, 2018, 37(1):41-50. LI P H, ZOU X Y, LOU J, et al. Pollution characteristics and evaluation of heavy metals around landfill in different seasons[J]. Environmental Chemistry, 2018, 37(1):1479-1485(in Chinese).
[14] 赵倩, 马琳, 刘翼飞, 等. 北京东南郊典型地层重金属分布特征与潜在生态风险[J]. 环境科学, 2016, 37(5):1931-1937. ZHAO Q, MA L, LIU Y F, et al. Distribution characteristics and potential ecological hazards assessment of soil heavy metals in typical soil profiles in southeast suburb of Beijing[J]. Environmental Sciences, 2016, 37(5):1931-1937(in Chinese).
[15] 何姜毅, 张东, 赵志琦. 豫北大田蔬菜种植区地下水重金属的分布特征及来源解析[J]. 环境化学, 2017, 36(7):1537-1546. HE J Y, ZHANG D, ZHAO Z Q. Distributions and sources of heavy metals in groundwater of vegetable fields in North Henan Province[J]. Environmental Chemistry, 2017, 36(7):1537-1546(in Chinese).
[16] WEI X, GAO B, WANG P, et al. Pollution characteristics and health risk assessment of heavy metals in street dusts from different functional area in Beijing, China[J]. Ecotoxicology and Environmental Safety, 2015, 112:186-192. [17] 刘丹, 赵永红, 周丹, 等. 赣南某钨矿区土壤重金属污染生态风险评价[J]. 环境化学, 2017, 36(7):1556-1567. LIU D, ZHAO Y H, ZHOU D, et al. Ecological risk assessment of heavy metals pollution in a tungsten mine soil in south of Jiangxi Province[J]. Environmental Chemistry, 2017, 36(7):1556-1567(in Chinese).
[18] 易昊旻, 周生路, 吴绍华, 等. 基于正态模糊数的区域土壤重金属污染综合评价[J]. 环境科学学报, 2013, 33(4):1127-1134. YI H M, ZHOU S L, WU S H, et al. An integrated assessment for regional heavy metal contamination in soil based on normal fuzzy number[J]. Acta Scientiae Circumstantiae, 2013, 33(4):1127-1134(in Chinese).
[19] 夏品华, 喻理飞, 寇永珍, 等. 贵州高原草海湿地土壤有机碳分布特征及其与酶活性的关系[J]. 环境科学学报, 2017, 37(4):1479-1485. XIA P H, YU L F, KOU Y Z, et al. Distribution characteristics of soil organic carbon and its relationship with enzyme activity in the Caohai wetland of the Guizhou Plateau[J]. Acta Scientiae Circumstantiae, 2017, 37(4):1479-1485(in Chinese).
[20] 杨延峰, 张国钢, 陆军, 等. 贵州草海越冬斑头雁日间行为模式及环境因素对行为的影响[J]. 生态学报, 2012, 32(23):7280-7288. YANG Y F, ZHANG G G, LU J, et al. Diurnal activity patterns and environmental factors on behaviors of Bar-headed Geese Anser indicus wintering at Caohai lake of Guizhou, China[J]. Acta Ecologica Sinica, 2012, 32(23):7280-7288(in Chinese).
[21] 夏品华, 喻理飞, 曹海鹏, 等. 贵州草海人工湿地系统硝化/反硝化作用研究[J]. 生态环境学报, 2015, 24(12):2045-2049. XIA P H, YU L, CAO H P, et al. Nitrification and denitrification in constructed wetlands of Caohai[J]. Ecology and Environmental Sciences, 2015, 24(12):2045-2049(in Chinese).
[22] 张家春, 林绍霞, 张清海, 等. 贵州草海耕地土壤与农作物中DDTs和HCHs残留及污染特征[J]. 农业环境科学学报, 2014, 33(7):1351-1357. ZHANG J C, LIN S X, ZHANG Q H, et al. Residue and pollution characteristics of HCHs and DDTs in crops and soils in Caohai watershed in Guizhou[J]. Journal of Agro-Environment Science, 2014, 33(7):1351-1357(in Chinese).
[23] 潘少兵, 任晓东. 草海国家级自然保护区水生植物群落的数量分类与排序分析[J]. 生物学杂志, 2010, 27(5):60-64. PAN S B, REN X D. An analysis on quantitative classification and ordination of aquatic plant communities in Caohai natural reserve[J]. Journal of Biology, 2010, 27(5):60-64(in Chinese).
[24] 潘鸿, 王洋, 晏妮, 等. 贵州草海水禽繁殖区水生植物群落及物种多样性初步研究[J]. 贵州师范大学学报:自然科学版, 2005, 23(2):15-19. PAN H, WANG Y, Y AN N, et al. A primary study of hydrophytecommunity structure and biodiversity at the waterfowl reproducing area of BoJiwan in Caohai lake[J]. Journal of Guizhou Normal University (Natural Science), 2005, 23(2):15-19(in Chinese).
[25] 林绍霞, 张清海, 郭媛, 等. 贵州草海沉积物重金属污染特征及潜在生态风险分析[J]. 农业环境科学学, 2012, 31(11):2236-2241. LIN S X, ZHANG Q H, GUO Y, et al. Pollution characteristics and potential ecological risk assessment of heavy metals in sediments of Caohai in Guizhou province, China[J]. Journal of Agro-Environment Science, 2012, 31(11):2236-2241(in Chinese).
[26] [27] 许正亮, 杨帮华, 刘文. 草海国家级自然保护区植被恢复与重建初探[J]. 内蒙古林业调查设计, 2008, 31(1):5-9. XU Z L, YANG B H, LIU W. Prelim inary studies on restoration and reconstitution of vegetation in Caohai national nature reservation area[J]. Inner Mongolia Forestry Survey Design, 2008, 31(1):5-9(in Chinese).
[28] 周静, 官加杰. 贵州草海国家级自然保护区生态旅游开发初步研究[J]. 林业调查规划, 2011, 36(5):49-52. ZHOU J, GUAN J J. Eco-tourism development of Caohai national nature reserve in Guizhou[J]. Forest Inventory and Planning, 2011, 36(5):49-52(in Chinese).
[29] 张建利, 吴华, 喻理飞,等. 贵州草海湿地流域典型喀斯特森林植物群落结构特征[J]. 南方农业学报, 2013, 44(3):471-477. ZHANG J L, WU H, YU L F, et al. Structure feature of typical Karst forest plant community in Caohai wetland watershed of Guizhou province[J]. Journal of Southern Agriculture, 2013, 44(3):471-477(in Chinese).
[30] 欧阳勇, 林昌虎, 何腾兵, 等. 贵州草海水体富营养化的植物修复研究[J]. 贵州科学, 2011, 29(6):21-25. OUYANG Y, LIN C H, HE T B, et al. Study on phytoremediation of eutrophication in Caohai lake of Guizhou[J]. Guizhou Science, 2011, 29(6):21-25(in Chinese).
[31] 龙加洪, 谭菊, 吴银菊, 等. 土壤重金属含量测定不同消解方法比较研究[J]. 中国环境监测, 2013, 29(1):123-126. LONG J H, TAN J, WU Y J, et al. A comparative study on the detection of heavy metal in soil with different digestion methods[J]. Environmental Monitoring in China, 2013, 29(1):123-126(in Chinese).
[32] 唐贵才, 刘明, 袁廷香. 贵州城市生活垃圾焚烧过程中重金属分布和迁移特征[J]. 生态环境学报, 2016, 25(4):686-691. TANG G C, LIU M, YUAN T X. Research on the distribution and migration rule of heavy metals in waste incineration in Guizhou city[J]. Ecology and Environmental Sciences, 2016, 25(4):686-691(in Chinese).
[33] 陈小敏, 朱保虎, 杨文, 等. 密云水库上游金矿区土壤重金属空间分布/来源及污染评价[J]. 环境化学, 2015, 34(12):2248-2256. CHEN X M, ZHU B H, YANG W, et al. Sources, spatial distribution and contamination assessments of heavy metals in gold mine area soils of Miyun reservoir upstream, Beijing, China[J]. Environmental Chemistry, 2015, 34(12):2248-2256(in Chinese).
[34] SWAINE D J. Why trace elements are important[J]. Fuel Processing Technology, 2000(65-66):21-33. [35] HAKANSON L. An ecological risk index for aquatic pollution control a sedimentological approach[J]. Water Research, 1980, 14(8):975-1001. [36] 方明, 吴友军, 刘红, 等. 长江口沉积物重金属的分布/来源及潜在生态风险评价[J]. 环境科学学报, 2013, 33(2):563-569. FANG M, WU Y J, LIU H, et al. Distribution, source and ecological risk assessment of heavy metals in sediments of the Yangtze river estuary[J]. Acta Scientiae Circumstantiae, 2013, 33(2):563-569(in Chinese).
[37] 范明毅, 杨皓, 黄先飞, 等. 典型山区燃煤型电厂周边土壤重金属形态特征及污染评价[J]. 中国环境科学, 2016, 36(8):2425-2436. FANG M Y, YANG H, HUANG X F, et al. Chemical forms and risk assessment of heavy metals in soils around a typical coal-fired power plant located in the mountainous area[J]. China Environmental Science, 2016, 36(8):2425-2436(in Chinese).
[38] [39] 石金芳, 张瑞雪, 吴攀, 等. 贵州省地表环境重金属空间分布特征研究[J]. 环保科技, 2015, 21(3):9-14. SHI J F, ZHANG R X, WU P. et al. Review on spatial distribution of heavy metals in supergene environment of Guizhou Province[J]. Environmental Protection and Technology, 2015, 21(3):9-14(in Chinese).
[40] 王小莉, 陈志凡, 魏张东, 等. 开封市城乡交错区农田土壤重金属污染及潜在生态风险评价[J]. 环境化学, 2018, 37(3):513-522. WANG X L, CHENG Z F, WEI Z D, et al. Heavy metal pollution and potential ecological risk assessment in agricultural soils located in the peri-urban area of Kaifeng City[J]. Environmental Chemistry, 2018, 37(3):513-522(in Chinese).
[41] 芦宝良, 陈克龙, 曹生奎, 等. 青海湖典型湿地土壤重金属空间分布特征[J]. 水土保持研究, 2012, 19(3):190-194. LU B L, CHEN K L, CAO S K, et al. Spatial distribution characteristics of soil heavy metals of wetlands in some representative regions around Qinghai lake[J]. Research of Soil and Water Conservation, 2012, 19(3):190-194(in Chinese).
[42] 蔡晓玲, 黄小柱, 廖德平. 草海国家级自然保护区耕地土壤化学性质分析[J]. 内蒙古农业科技, 2010(3):60-61. CAI X L,HUANG X Z,LIAO D P. Analysis of chemical properties of farmland soil in Caohai national nature reserve[J]. Inner Mongolia Agricultural Science and Technology, 2010 (3):60-61(in Chinese).
[43] 潘胜强, 王铎, 吴山, 等. 土壤理化性质对重金属污染土壤改良的影响分析[J]. 环境工程, 2014, 32(s1):600-603. PAN S Q,WANG D, WU S, et al. Impact of soil properties on Improvement of Heavy metal contaminated soil[J]. Environmental Engineering, 2014, 32(s1):600-603(in Chinese).
[44] 段素明, 黄先飞, 胡继伟, 等. 贵州草海湿地植物根际沉积物磷素形态特征[J]. 环境科学研究, 2013, 26(7):743-749. DUAN S M, HUANG X F, HU J W, et al. Study on speciation of phosphorus in rhizosphere sediments from Caohai wetland[J]. Research of Environmental Sciences, 2013, 26(7):743-749(in Chinese).
[45] 杨勇, 刘爱军, 朝鲁孟其其格, 等. 锡林郭勒露天煤矿矿区草原土壤重金属分布特征[J]. 生态环境学报, 2016, 25(5):885-892. YANG Y LIU A J CHAO L M Q Q G, et al. Spatial distribution of soil heavy metals of open cut coal mining in inner Mongolia Xilingol typical steppe[J]. Ecology and Environmental Sciences, 2016, 25(5):885-892(in Chinese).
[46] 许兴斌, 焦黎, 王勇辉. 夏尔西里自然保护区土壤重金属相关性分析及污染风险评价[J]. 水土保持研究, 2015, 22(5):336-341. XU X B, JIAO L, WANG Y H. Risk evaluation and correlation Analysis of soil heavy metal contamination in Xiaerxili nature reserve[J]. Research of Soil and Water Conservation, 2015, 22(5):336-341(in Chinese).
[47] 侯凤兰, 吕光辉, 马辉英, 等. 乌鲁木齐水磨河沿岸土壤痕量金属污染特征与来源解析[J]. 环境化学, 2017, 36(11):2451-2461. HOU F L, LV G H, MA H Y, et al. Contamination characterization and source apportionment of trace metals in riparian soils of Shuimo River in Urumqi[J]. Environmental Chemistry, 2017, 36(11):2451-2461(in Chinese).
[48] YE C, LI S, ZHANG Y, et al. Assessing heavy metal pollution in the water level fluctuation zone of China's three gorges reservoir using geochemical and soil microbial approaches[J]. Environmental Monitoring and Assessment, 2013, 185(1):231-240. [49] FACCHINELI A, SACCHI E, MALLEN L. Multivariate statistical and GIS-based approach to identify heavy metal sources in soil[J]. Environmental Pollution, 2001, 114(3):313-324. [50] Gray C W, MCLAREN R G, ROBERTS A H C. The effect of long-term phosphatic fertilizer applications on the amounts and forms of cadmium in soils under pasture in New Zealand[J]. Nutrient Cycling in Agroecosystems, 1999, 54(3):267-277. [51] 林文杰. 土法炼锌区生态退化与重金属污染[J]. 生态环境学报, 2009, 18(1):149-153. LIN W J. Ecological degeneration and heavy metals pollution in zinc smelting areas[J]. Ecology and Environmental Sciences, 2009, 18(1):149-153(in Chinese).
[52] 王美, 李书田. 肥料重金属含量状况及施肥对土壤和作物重金属富集的影响[J]. 植物营养与肥料学报, 2014, 20(2):466-480. WANG M, LI S T. Heavy metals in fertilizers and effect of the fertilization on heavy metal accumulation in soils and crops[J]. Journal of Plant Nutrition and Fertilizer, 2014, 20(2):466-480(in Chinese).
[53] 宋以龙, 曾艳, 杨海全, 等. 贵州草海沉积物重金属时空分布特征与生态风险评价[J]. 生态学杂志, 2016, 35(7):1849-1856. SONG Y L, ZENG Y, YANG H Q, et al. Spatiotemporal distribution and potential ecological risk assessment of heavy metals in the sediments of lake Caohai, Guizhou, China[J]. Chinese Journal of Ecology, 2016, 35(7):1849-1856(in Chinese).
[54] 陶思明. 草海保护区的压力和可持续发展管理[J]. 生态与自然保护, 1999, 1:25-28. TAO S M. Pressures of Caohai reservation and sustainable management[J]. Ecology and Natural Conservation, 1999 , 1:25-28(in Chinese).
期刊类型引用(15)
1. 刘玮晶,许伟伟,任静华,华明,崔晓丹,李文博,周强,汪子意,汪媛媛. 长三角城市群典型区土壤重金属时空变异及源解析. 环境工程学报. 2025(02): 414-425 . 百度学术
2. 蒋艳萍,赵芳,彭耀,尹宇莹,茹赛红,胡芳. 基于总量和有效态的长沙市土壤重金属污染特征及生态风险评价. 绿色科技. 2024(14): 102-106 . 百度学术
3. 罗雨虹,朱四喜,夏国栋,赵斌,王众. 废弃铬渣厂土壤理化性质对微生物多样性的影响. 有色金属(冶炼部分). 2022(06): 91-100 . 百度学术
4. 李强,姚万程,赵龙,张朝,张恩月,苏迎庆,刘庚. 燃煤工业区不同土地利用类型土壤汞含量污染评价. 环境科学. 2022(07): 3781-3788 . 百度学术
5. 李娉,董艺博,谭玉兰,周丽,陈超. 对喀斯特地区不同利用方式下土壤质量的评价. 东北农业科学. 2022(06): 59-64 . 百度学术
6. 王柏淳,朱四喜,赵斌,李武江. 贵州锁黄仓湿地沉积物重金属空间分布及生态风险评价. 水生态学杂志. 2021(01): 49-57 . 百度学术
7. 黄昌辰,温汉辉,蔡立梅,罗杰,蒋慧豪. 广东揭阳市土壤铜的分布特征及其影响因素. 现代地质. 2021(01): 293-300 . 百度学术
8. 李武江,朱四喜. 某矿区农田土壤重金属分布特征与生态风险评价. 有色金属(冶炼部分). 2021(03): 93-101 . 百度学术
9. 沈洪艳,安冉,师华定,刘孝阳,张安迪. 湖南省某典型流域农用地土壤重金属污染及影响因素. 环境科学研究. 2021(03): 715-724 . 百度学术
10. 董艺博,陈超,周丽,杨丰,谭玉兰. 罗甸县不同土地利用类型对土壤重金属含量的影响. 西南农业学报. 2021(02): 392-399 . 百度学术
11. 袁刚毅,郭其强,杨瑞. 草海国家级自然保护区森林群落优势种群数量动态及物种多样性研究. 西北植物学报. 2021(07): 1229-1239 . 百度学术
12. 李武江,朱四喜,王众,赵斌. 西南山地煤矿区耕地土壤-农作物重金属富集及健康风险评价. 中国无机分析化学. 2021(05): 22-30 . 百度学术
13. 陈丹丹,谭璐,聂紫萌,万自学,舒倩,杨海君. 湖南典型金属冶炼与采选行业企业周边土壤重金属污染评价及源解析. 环境化学. 2021(09): 2667-2679 . 本站查看
14. 师小平,陈银萍,李玉强,王旭洋,余沛东,牛亚毅. 北方农牧交错典型区土壤重金属空间分布及污染风险评价. 生态科学. 2020(06): 7-15 . 百度学术
15. 魏亚龙. 连续提取法对土地土壤重金属形态特征的研究. 环境与发展. 2019(05): 117-118 . 百度学术
其他类型引用(19)
-

计量
- 文章访问数: 1378
- HTML全文浏览数: 1352
- PDF下载数: 140
- 施引文献: 34