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新型溴系阻燃剂环境污染现状研究进展

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童艺, 程伊雪, 吴冠履, 张海燕, 潘远江, 冯鸿儒. 新型溴系阻燃剂环境污染现状研究进展[J]. 环境化学, 2021, (1): 83-101. doi: 10.7524/j.issn.0254-6108.2020042501
引用本文: 童艺, 程伊雪, 吴冠履, 张海燕, 潘远江, 冯鸿儒. 新型溴系阻燃剂环境污染现状研究进展[J]. 环境化学, 2021, (1): 83-101. doi: 10.7524/j.issn.0254-6108.2020042501
shu
TONG Yi, CHENG Yixue, WU Guanlyu, ZHANG Haiyan, PAN Yuanjiang, FENG Hongru. Current research progress on environmental pollution of novel brominated flame retardant[J]. Environmental Chemistry, 2021, (1): 83-101. doi: 10.7524/j.issn.0254-6108.2020042501
Citation: TONG Yi, CHENG Yixue, WU Guanlyu, ZHANG Haiyan, PAN Yuanjiang, FENG Hongru. Current research progress on environmental pollution of novel brominated flame retardant[J]. Environmental Chemistry, 2021, (1): 83-101. doi: 10.7524/j.issn.0254-6108.2020042501
shu

新型溴系阻燃剂环境污染现状研究进展

  • 1. 浙江大学化学系, 杭州, 310027;

  • 2. 浙江大学药学院, 杭州, 310058;

  • 3. 浙江工业大学环境学院, 杭州, 310032

    • 通讯作者: 潘远江, E-mail: panyuanjiang@zju.edu.cn ;  冯鸿儒, E-mail: fenghongru@zju.edu.cn
  • 基金项目:

    国家自然科学基金（21906137）资助.

Current research progress on environmental pollution of novel brominated flame retardant

  • 1. Department of Chemistry, Zhejiang University, Hangzhou, 310027, China;

  • 2. College of Pharmaceutical Sciences, Zhejiang University, Hangzhou, 310058, China;

  • 3. College of Environment, Zhejiang University of Technology, Hangzhou, 310032, China

    • Corresponding authors: PAN Yuanjiang, panyuanjiang@zju.edu.cn ;  FENG Hongru, fenghongru@zju.edu.cn
  • Fund Project: Supported by the National Natural Science Foundation of China (21906137).

  • 摘要: 新型溴系阻燃剂（NBFRs，novel brominated flame retardants）作为传统溴系阻燃剂的替代品已广泛应用于电子产品、纺织品、家具等商品中，随着这些商品的生产、使用和处置，NBFRs不可避免地释放到环境中，给环境和人体带来潜在的危害.部分NBFRs可通过摄食和呼吸作用进入人体对人体产生一定危害，已被证明具有潜在的生物毒性.而NBFRs的环境污染现状研究对控制NBFRs的污染具有重要意义.近年来有不少研究者对不同环境基质中的NBFRs进行了定量测定.基于这些研究成果，本文综述了近年来环境中NBFRs的研究现状、进展，重点介绍了水体、沉积物和大气中NBFRs的含量分布.多种类型水体中NBFRs的浓度水平在ng·L-1至μg·L-1之间，浓度受地区工业生产和季节等因素影响，且不同污水处理系统对水体中NBFRs的去除效率具有一定差异；NBFRs倾向于分布在富含有机碳的介质中，沉积物中NBFRs的含量在ng·g-1至μg·g-1级别，浓度与地区工业生产、化合物性质以及总有机碳含量等因素有关；大气中的NBFRs倾向吸附于颗粒相中，在两相中的含量分别为pg·m-3和ng·g-1级别，其含量受环境因素影响较为复杂.
    Abstract: Novel brominated flame retardants (NBFRs), as substitutes for traditional brominated flame retardants, have been widely used in electronic products, textiles, and furniture. The emission of NBFRs into environment by the production, use and dispose of these products is inevitable, which may have adverse effects to the environment and human body. Several NBFRs have been proved to have potentially ecotoxicity and can cause adverse effect to human through ingestion and inhalation. The studies of environmental pollution caused by NBFRs have great significance in providing references for pollution control. The review attempted to summarize current research progress on environmental pollution of NBFRs. The occurrence of NBFRs in water, air, dust, soil, sediment and sludge were documented. Concentrations of NBFRs in water ranges from ng·L-1 to μg·L-1, which were influenced by regional industrial manufacture, season and other factors. Moreover, different wastewater treatment processes had different removal efficiency for NBFRs in wastewater. NBFRs tended to partition to medium with higher content of organic carbon and were detected in the range from ng·g-1 to μg·g-1 in sediment, dust and sewage sludge. The concentration was related to regional industrial manufacture, chemical properties of NBFRs and total organic carbon. NBFRs tended to be adsorbed in atmospheric particulate, and the concentrations in air and dust are pg·m-3 and ng·g-1, respectively, and the concentration levels were influenced by various factors.
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  • [1] TOMS L M L,HEARN L, KENNEDY K, et al. Concentrations of polybrominated diphenyl ethers (PBDEs) in matched samples of human milk, dust and indoor air[J]. Environment International, 2009, 35(6):864-869.
    [2] LAM J C W, LAM P K S. Occurrence and ecological risk of halogenated flame retardants (HFRs) in coastal zones[J]. Comprehensive Analytical Chemistry, 2015, 67:389-409.
    [3] 苏冠勇. 多溴联苯醚及其衍生物的环境调查、致毒机制及其基于芳烃受体活性的健康风险评估研究[D]. 南京:南京大学, 2013. SU G Y. Environmental investigation and toxicological mechanism of polybrominated diphenyl ethers and their derivatives and health risk assessment based on aromatic receptor activity[D]. Nangjing:Nanjing University, 2013(in Chinese).
    [4] UNEP. SC-4/14:Listing of hexabromodiphenyl ether and heptabromodiphenyl ether[R]. Stockholm Convention Organic on Persistent Pollutants:Persistent Organic Pollutants Review Committee Fourth meeting, 2009.
    [5] UNEP. SC-4/18:Listing of tetrabromodiphenyl ether and pentabromodiphenyl ether[R]. Stockholm Convention Organic on Persistent Pollutants:Persistent Organic Pollutants Review Committee Fourth meeting, 2009.
    [6] UNEP. SC-8/10:Listing of decabromodiphenyl ether (commercial mixture, c-decaBDE)[R]. Stockholm Convention Organic on Persistent Pollutants:Persistent Organic Pollutants Review Committee Eighth meeting, 2017.
    [7] UNEP. SC-6/13:Listing of hexabromocyclododecane[R]. Stockholm Convention Organic on Persistent Pollutants:Persistent Organic Pollutants Review Committee Sixth meeting, 2013.
    [8] COVACI A, HARRAD S, ABDALLAH A E, et al. Novel brominated flame retardants:A review of their analysis, environmental fate and behaviour[J]. Environment International, 2011, 37(2):532-556.
    [9] MCGRATH T J, MORRISON P D, BALL A S, et al. Detection of novel brominated flame retardants (NBFRs) in the urban soils of Melbourne, Australia[J]. Emerging Contaminants, 2017, 3(1):23-31.
    [10] YU G, BU Q, CAO Z, et al. Brominated flame retardants (BFRs):A review on environmental contamination in China[J]. Chemosphere, 2016, 150:479-490.
    [11] 李英明, 王亚群, 江桂斌. 新型持久性有机污染物PBDEs概述[J]. 实验与分析, 2008(1):38-39. LI Y M, WANG Y Q, JIANG G B. Overview of new persistent organic pollutant PBDEs[J]. Experiment and Analysis, 2008

    (1):38-39(in Chinese).

    [12] 陈田, 余旸帆, 白易, 等. 十溴二苯乙烷污染水平及毒性研究进展[J]. 中国预防医学杂志, 2018, 52(8):855-861.

    CHEN T, YU Y F, BAI Y, et al. Decabromodiphenyl ethane:A review of its pollution levels and toxicity[J]. China Jounal Prevent Method, 2018, 52(8):855-861(in Chinese).

    [13] CANADA GAZETTE. Order adding toxic substances to schedule 1 to the Canadian Environmental Protection Act, 1999[EB/OL].[2019-6-29]. http://www.gazette.gc.ca/rp-pr/p1/2019/2019-06-29/html/reg2-eng.html#reg
    [14] ZHANG X, LI J, CHEN M J, et al. Toxicity of the brominated flame retardant tris-(2,3-dibromopropyl) isocyanurate in zebrafish (Danio rerio)[J]. Chinese Science Bulletin, 2011, 56(15):1548-1555.
    [15] EZECHIÁŠ M, SVOBODOVÁ K, CAJTHAML T. Hormonal activities of new brominated flame retardants[J]. Chemosphere, 2012, 87(7):820-824.
    [16] XIONG P, YAN X T, ZHU Q Q, et al. A review of environmental occurrence, fate, and toxicity of novel brominated flame retardants[J]. Environment Science & Technology, 2019, 53(23):13551-13569.
    [17] POLO M, LLOMPART M, GARCIA-JARES C, et al. Development of a solid-phase microextraction method for the analysis of phenolic flame retardants in water samples[J]. Journal of Chromatography A, 2006, 1124(1/2):11-21.
    [18] NIU D, QIU Y, DU X, et al. Novel brominated flame retardants in house dust from Shanghai, China:Levels, temporal variation, and human exposure[J]. Environmental Sciences Europe, 2019, 31(1):6.
    [19] PRADHAN A, ASNAKE S, KHARLYNGDOH J B, et al. In silico and biological analysis of anti-androgen activity of the brominated flame retardants ATE, BATE and DPTE in zebrafish[J]. Chemico Biological Interactions, 2015, 233:35-45.
    [20] KHALAF H, LARSSON A, BERG H, et al. Diastereomers of the brominated flame retardant 1,2-dibromo-4-(1,2 dibromoethyl)cyclohexane induce androgen receptor activation in the HepG2 hepatocellular carcinoma cell line and the LNCaP prostate cancer cell line[J]. Environ Health Perspect, 2009, 117(12):1853-1859.
    [21] LARSSON A, ERIKSSON L A, ANDERSSON P L, et al. Identification of the brominated flame retardant 1,2-dibromo-4-(1,2-dibromoethyl)cyclohexane as an androgen agonist[J]. J Med Chem, 2006, 49(25):7366-7372.
    [22] GANCI A P, VANE C H, ABDALLAH A E, et al. Legacy PBDEs and NBFRs in sediments of the tidal River Thames using liquid chromatography coupled to a high resolution accurate mass Orbitrap mass spectrometer[J]. Science of the Total Environment, 2019, 658:1355-1366.
    [23] PAPACHLIMITZOU A, BARBER J L, LOSADA S, et al. A review of the analysis of novel brominated flame retardants[J]. J. Chromatogr A, 2012, 1219:15-28.
    [24] LÓPEZ P, BRANDSMA S A, LEONARDS P E G, et al. Methods for the determination of phenolic brominated flame retardants, and by-products, formulation intermediates and decomposition products of brominated flame retardants in water[J]. J Chromatogr A, 2009, 1216(3):334-345.
    [25] ZHOU S N, REINER E J, MARVIN C, et al. Development of liquid chromatography atmospheric pressure chemical ionization tandem mass spectrometry for analysis of halogenated flame retardants in wastewater[J]. Anal Bioanal Chem, 2010, 396(3):1311-1320.
    [26] LAW K, HALLDORSON T, DANELL R, et al. Bioaccumulation and trophic transfer of some brominated flame retardants in a Lake Winnipeg (Canada) food web[J]. Environmental Toxicology & Chemistry, 2006, 25(8):2177-2186.
    [27] XIE Z, MÖLLER A, AHRENS L, et al. Brominated flame retardants and Dechlorane Plus in air and sea water of the Atlantic Ocean and the Antarctic[C]//Proceedings of the BFR2010 Conference, Kyoto, Japan, 2010.
    [28] HE M J, LUO X J, CHEN M Y, et al. Bioaccumulation of polybrominated diphenyl ethers and decabromodiphenyl ethane in fish from a river system in a highly industrialized area, South China[J]. Science of the Total Environment, 2012,419:109-115.
    [29] WANG Y, WU X, ZHAO H, et al. Characterization of PBDEs and novel brominated flame retardants in seawater near a coastal mariculture area of the Bohai Sea, China[J]. Science of the Total Environment, 2017, 580:1446-1452.
    [30] HOU L, JIANG J, GAN Z, et al. Spatial distribution of organophosphorus and brominated flame retardants in surface water, sediment, groundwater, and wild Fish in Chengdu, China[J]. Archives of Environmental Contamination & Toxicology, 2019, 77(2):279-290
    [31] MÖLLER A, XIE Z,BUSCH J,et al. Non-PBDE brominated flame retardants and Dechlorane Plus in air and seawater of the Arctic[C]//Proceedings of the BFR2010 Conference, Kyoto, Japan, 2010.
    [32] RUAN T, WANG Y W, WANG C, et al. Identification and evaluation of a eovel heterocyclic brominated flame retardant tris(2,3-dibromopropyl) isocyanurate in environmental matrices near a manufacturing plant in southern China[J]. Environmental Science & Technology, 43(9):3080-3086.
    [33] KHAN M U, LI J, ZHANG G, et al. First insight into the levels and distribution of flame retardants in potable water in Pakistan:An underestimated problem with an associated health risk diagnosis[J]. Science of the Total Environment, 2016, 565:346-359.
    [34] LI B, WANG K L, MA X, et al. Deca-BDE and alternative halogenated flame retardants in a wastewater treatment plant in Harbin (2009-2016):Occurrence, temporal trends, seasonal variation, and fate[J]. Science of the Total Environment, 2018, 625:1156-1163.
    [35] RUAN Y, ZHANG K, LAM J C W, et al. Stereoisomer-specific occurrence, distribution, and fate of chiral brominated flame retardants in different wastewater treatment systems in Hong Kong[J]. Journal of Hazardous Materials, 2019, 374:211-218.
    [36] FENG H, RUAN Y, WU R, et al. Occurrence of disinfection by-products in sewage treatment plants and the marine environment in Hong Kong[J]. Ecotoxicology and Environmental Safety, 2019, 181:404-411.
    [37] KIM M, GUERRA P, ALAEE M, et al. Occurrence and fate of four novel brominated flame retardants in wastewater treatment plants[J]. Environmental Science & Pollution Research, 2014, 21(23):13394-13404.
    [38] MAN Y B, CHOW K L, MAN M, et al. Profiles and removal efficiency of polybrominated diphenyl ethers by two different types of sewage treatment work in Hong Kong[J]. Science of the Total Environment, 2015, 505:261-268.
    [39] SHANMUGANATHAN M, ZHANG Z, SVERKO E, et al. Analysis of halogenated flame retardants in Canadian wastewater treatment plants using gas chromatography-tandem mass spectrometry (GC-MS/MS)[J]. Water Quality Research Journal of Canada, 2018, 53(4):167-180.
    [40] QIU X, MARVIN C H, HITES R A. Dechlorane plus and other flame retardants in a sediment core from lake Ontario[J]. Environmental Science & Technology, 2007, 41(17):6014-6019.
    [41] HOH E, ZHU L, HITES R A. Novel flame retardants, 1,2-bis(2,4,6-tribromophenoxy)ethane and 2,3,4,5,6-pentabromoethylbenzene, in United States' environmental samples[J]. Environmental Science & Technology, 2005, 39(8):2472-2477.
    [42] SHI T, CHEN S J, LUO X J, et al. Occurrence of brominated flame retardants other than polybrominated diphenyl ethers in environmental and biota samples from southern China[J]. Chemosphere, 2009, 74(7):910-916.
    [43] KÖPPEN R, BECKER R, JUNG C, et al. Investigation of extraction procedures and HPLC-DAD/MS for the determination of the brominated flame retardant tetrabromobisphenol A bis(2,3-dibromopropylether) in environmental samples[J]. Analytical & Bioanalytical Chemistry, 2006, 384(7/8):1485-1492.
    [44] KIERKEGAARD A, BJÖRKLUND J, FRIDÉN U. Identification of the flame retardant decabromodiphenyl ethane in the environment[J]. Environmental Science & Technology, 2004, 38(12):3247-3253.
    [45] SUTTON R, CHEN D, SUN J, et al. Characterization of brominated, chlorinated, and phosphate flame retardants in San Francisco Bay, an urban estuary.[J]. Science of the Total Environment, 2019, 652:212-223.
    [46] ZHANG X L, LUO X J, CHEN S J, et al. Spatial distribution and vertical profile of polybrominated diphenyl ethers, tetrabromobisphenol A, and decabromodiphenylethane in river sediment from an industrialized region of South China[J]. Environmental Pollution, 2009, 157(6):1917-1923.
    [47] ILYAS M, SUDARYANTO A, SETIAWAN I E, et al. Characterization of polychlorinated biphenyls and brominated flame retardants in surface soils from Surabaya, Indonesia[J]. Chemosphere, 2011, 83(6):783-791.
    [48] MCGRATH T J, BALL A S, CLARKE B O. Critical review of soil contamination by polybrominated diphenyl ethers (PBDEs) and novel brominated flame retardants (NBFRs); concentrations, sources and congener profiles[J]. Environmental Pollution, 2017, 230:741-757.
    [49] WANG S, WANG Y, SONG M, et al. Distributions and compositions of old and emerging flame retardants in the rhizosphere and non-rhizosphere soil in an e-waste contaminated area of South China[J]. Environmental Pollution, 2016, 208:619-625.
    [50] RICKLUND N, KIERKEGAARD A, MCLACHLAN M S, et al. Mass balance of decabromodiphenyl ethane and decabromodiphenyl ether in a WWTP[J]. Chemosphere, 2009, 74(3):389-394.
    [51] GORGA M, MARTINEZ E, GINEBREDA A, et al. Determination of PBDEs, HBB, PBEB, DBDPE, HBCD, TBBPA and related compounds in sewage sludge from Catalonia (Spain)[J]. Science of the Total Environment, 2013, 444:51-59.
    [52] MATTSSON P E, NORSTRÖM Å, RAPPE C. Identification of the flame retardant pentabromotoluene in sewage sludge.[J]. J Chromatogr, 1975, 111:209-213.
    [53] WEISSER M. Investigations on the contamination of municipal sewage sludges with organic pollutants[C]//Universität Karlsruhe (Schriftenreihe ISWW, 63); 1992.
    [54] KLOSTERHAUS S, KONSTANTINOV A, STAPLETON H. Characterization of the brominated chemicals in a PentaBDE replacement mixture and their detection in biosolids collected from two San Francisco Bay area wastewater treatment plants[R]. Northern California Society of Environmental Toxicology and Chemistry.
    [55] OBERG K, WARMAN K, OBERG T. Distribution and levels of brominated flame retardants in sewage sludge[J]. Chemosphere, 2002, 48(8):805-809.
    [56] 张宏莉,仇雁翎, 葛元新, 等. 中国大气环境中溴代阻燃剂污染特征研究进展[J]. 环境科学与技术, 2016, 39(3):192-199.

    ZHANG H L, QIU Y L, GE Y X, el a1. Study progress on pollution characteristics of brominated flame retardants BFRs in China atmospheric environment[J]. Environmental Science &Technology, 2016, 39(3):192-199(in Chinese).

    [57] SJÖDIN A, CARLSSON H, THURESSON K, et al. Flame retardants in indoor air at an electronics recycling plant and at other work environments[J]. Environmental Science & Technology, 2001, 35(3):448-454.
    [58] STAPLETON H M, ALLEN J G, KELLY S M, et al. Alternate and new brominated flame retardants detected in U.S. house dust[J]. Environmental Science and Technology, 2008, 42(18):6910-6916.
    [59] ZHU J, HOU Y, FENG Y L, et al. Identification and determination of hexachlorocyclopentadienyl- dibromocyclooctane (HCDBCO) in residential indoor air and dust:A previously unreported halogenated flame retardant in the environment[J]. Environmental Science & Technology, 2008, 42(2):386-391.
    [60] SUN J, XU Y, ZHOU H, et al. Levels, occurrence and human exposure to novel brominated flame retardants (NBFRs) and dechlorane plus (DP) in dust from different indoor environments in Hangzhou, China[J]. Science of the Total Environment, 2018, 631/632:1212-1220.
    [61] SAITO I, ONUKI A, SETO H. Indoor organophosphate and polybrominated flame retardants in Tokyo[J]. Indoor Air, 2007, 17(1):28-36.
    [62] JULANDER A, WESTBERG H, ENGWALL M, et al. Distribution of brominated flame retardants in different dust fractions in air from an electronics recycling facility[J]. Science of the Total Environment, 2005, 350(1/3):151-160.
    [63] AL-OMRAN L S, HARRAD S. Distribution pattern of legacy and "novel" brominated flame retardants in different particle size fractions of indoor dust in Birmingham, United Kingdom[J]. Chemosphere, 2016, 157:124-131.
    [64] VENIER M, HITES R A. Flame retardants in the atmosphere near the Great Lakes[J]. Environmental Science & Technology, 2008, 42(13):4745-4751.
    [65] ZHANG W, WANG P, ZHU Y, et al. Brominated flame retardants in atmospheric fine particles in the Beijing- Tianjin-Hebei region, China:Spatial and temporal distribution and human exposure assessment[J]. Ecotoxicology and Environmental Safety, 2019, 171:181-189.
    [66] ZHAO J, WANG P, WANG C, et al. Novel brominated flame retardants in West Antarctic atmosphere (2011-2018):Temporal trends, sources and chiral signature[J]. Science of the Total Environment, 2020, 720:137557.
    [67] YU Y, HUNG H, ALEXANDROU N, et al. Multiyear measurements of flame retardants and organochlorine pesticides in air in Canada's western Sub-Arctic[J]. Environmental Science & Technology, 2015, 49(14):8623-8630.
    [68] MA W L, LI W L, ZHANG Z F, et al. Occurrence and source apportionment of atmospheric halogenated flame retardants in Lhasa City in the Tibetan Plateau, China[J]. Science of the Total Environment, 2017, 607/608:1109-1116.
    [69] MCGRATH T J, MORRISON P D, BALL A S, et al. Concentrations of legacy and novel brominated flame retardants in indoor dust in Melbourne, Australia:An assessment of human exposure[J]. Environment International, 2018, 113:191-201.
    [70] LEE H K, KANG H, LEE S, et al. Human exposure to legacy and emerging flame retardants in indoor dust:A multiple-exposure assessment of PBDEs[J]. Science of the Total Environment, 2020, 719:137386.
    [71] WANG Y, ZHANG Y, TAN F, et al. Characteristics of halogenated flame retardants in the atmosphere of Dalian, China[J]. Atmospheric Environment, 2020, 223:117219.
    [72] YADAV I C, DEVI N L, KUMAR A, et al. Airborne brominated, chlorinated and organophosphate ester flame retardants inside the buildings of the Indian state of Bihar:Exploration of source and human exposure[J]. Ecotoxicology and Environmental Safety, 2020,191:110212.
    [73] TORRE A DELA, NAVARRO I, SANZ P, et al. Organophosphate compounds, polybrominated diphenyl ethers and novel brominated flame retardants in European indoor house dust:Use, evidence for replacements and assessment of human exposure[J]. Journal of Hazardous Materials, 2020, 382:121009.
    [74] ANH H Q, WATANABE I, TUE N M, et al. Polyurethane foam-based passive air sampling for simultaneous determination of POP- and PAH-related compounds:A case study in informal waste processing and urban areas, northern Vietnam[J]. Chemosphere, 2020,247:125991.
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  • 收稿日期:  2020-04-25
童艺, 程伊雪, 吴冠履, 张海燕, 潘远江, 冯鸿儒. 新型溴系阻燃剂环境污染现状研究进展[J]. 环境化学, 2021, (1): 83-101. doi: 10.7524/j.issn.0254-6108.2020042501
引用本文: 童艺, 程伊雪, 吴冠履, 张海燕, 潘远江, 冯鸿儒. 新型溴系阻燃剂环境污染现状研究进展[J]. 环境化学, 2021, (1): 83-101. doi: 10.7524/j.issn.0254-6108.2020042501
shu
TONG Yi, CHENG Yixue, WU Guanlyu, ZHANG Haiyan, PAN Yuanjiang, FENG Hongru. Current research progress on environmental pollution of novel brominated flame retardant[J]. Environmental Chemistry, 2021, (1): 83-101. doi: 10.7524/j.issn.0254-6108.2020042501
Citation: TONG Yi, CHENG Yixue, WU Guanlyu, ZHANG Haiyan, PAN Yuanjiang, FENG Hongru. Current research progress on environmental pollution of novel brominated flame retardant[J]. Environmental Chemistry, 2021, (1): 83-101. doi: 10.7524/j.issn.0254-6108.2020042501
shu

新型溴系阻燃剂环境污染现状研究进展

    通讯作者: 潘远江, E-mail: panyuanjiang@zju.edu.cn ;  冯鸿儒, E-mail: fenghongru@zju.edu.cn
  • 1. 浙江大学化学系, 杭州, 310027;
  • 2. 浙江大学药学院, 杭州, 310058;
  • 3. 浙江工业大学环境学院, 杭州, 310032
  • 收稿日期:  2020-04-25
基金项目:

国家自然科学基金（21906137）资助.

摘要: 新型溴系阻燃剂（NBFRs，novel brominated flame retardants）作为传统溴系阻燃剂的替代品已广泛应用于电子产品、纺织品、家具等商品中，随着这些商品的生产、使用和处置，NBFRs不可避免地释放到环境中，给环境和人体带来潜在的危害.部分NBFRs可通过摄食和呼吸作用进入人体对人体产生一定危害，已被证明具有潜在的生物毒性.而NBFRs的环境污染现状研究对控制NBFRs的污染具有重要意义.近年来有不少研究者对不同环境基质中的NBFRs进行了定量测定.基于这些研究成果，本文综述了近年来环境中NBFRs的研究现状、进展，重点介绍了水体、沉积物和大气中NBFRs的含量分布.多种类型水体中NBFRs的浓度水平在ng·L-1至μg·L-1之间，浓度受地区工业生产和季节等因素影响，且不同污水处理系统对水体中NBFRs的去除效率具有一定差异；NBFRs倾向于分布在富含有机碳的介质中，沉积物中NBFRs的含量在ng·g-1至μg·g-1级别，浓度与地区工业生产、化合物性质以及总有机碳含量等因素有关；大气中的NBFRs倾向吸附于颗粒相中，在两相中的含量分别为pg·m-3和ng·g-1级别，其含量受环境因素影响较为复杂.

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