苦卤-鸟粪石沉淀法预处理垃圾渗滤液

商平; 刘涛利; 刘彦博

环境化学

苦卤-鸟粪石沉淀法预处理垃圾渗滤液

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商平, 刘涛利, 刘彦博. 苦卤-鸟粪石沉淀法预处理垃圾渗滤液[J]. 环境化学, 2010, 29(6): 1111-1115.

引用本文:

商平, 刘涛利, 刘彦博. 苦卤-鸟粪石沉淀法预处理垃圾渗滤液[J]. 环境化学, 2010, 29(6): 1111-1115.

SHANG Ping, LIU Taoli, LIU Yanbo. PRETREATMENT OF LANDFILL LEACHATE BY THE BITTERN- MAGNESIUM AMMONIUM PHOSPHATE PRECIPITATION METHOD[J]. Environmental Chemistry, 2010, 29(6): 1111-1115.

Citation:

SHANG Ping, LIU Taoli, LIU Yanbo. PRETREATMENT OF LANDFILL LEACHATE BY THE BITTERN- MAGNESIUM AMMONIUM PHOSPHATE PRECIPITATION METHOD[J]. Environmental Chemistry, 2010, 29(6): 1111-1115.

苦卤-鸟粪石沉淀法预处理垃圾渗滤液

1.
天津市海洋资源与化学重点实验室, 天津科技大学环境科学与工程系, 天津, 300457;
2.
天津泰达环保有限公司, 天津, 300222
基金项目:
天津市科技支撑计划重点项目(08ZCKFSH01600),天津市农业科技成果转化与推广项目(0802020)

PRETREATMENT OF LANDFILL LEACHATE BY THE BITTERN- MAGNESIUM AMMONIUM PHOSPHATE PRECIPITATION METHOD

1.
Tianjin Key laboratory of Marine Resources & Chemistry, Department of Environmental Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457, China;
2.
Tianjin Teda Environment Co., Ltd. Tianjin, 300222, China
Fund Project:

摘要: 以苦卤为新型镁沉淀剂,改性沸石为晶种,对鸟粪石沉淀法预处理高浓度氨氮垃圾渗滤液进行实验研究.结果表明:当n(Mg):n(N):n(P)=1.3:1.0:1.1,氨氮去除率为96.2%;铁沸石晶种在3.5g/150ml时氨氮的去除率增加到了97.88%.对新型镁沉淀剂成本分析表明,苦卤和改性沸石作鸟粪石沉淀剂和晶种是可行的.
- 鸟粪石沉淀法(MAP) /
- 苦卤 /
- 晶种 /
- 垃圾渗滤液 /
- 预处理
Abstract: A new magnesium ammonium phosphate (MAP) method is described as a pretreatment for landfill leachates with highly concentrated ammonia nitrogen, with Na2HPO4 as phosphate ions and the bittern as a new substitute for magnesium precipitation agent. Within the time of 25 min, under the conditions of pH8.5, n(Mg2+):n(NH4+):n(PO43-) = 1.3:1:1.1, the removal rate of NH3-N at the stirring speed 250r·min-1can remain as high as 96.2%, while the residual phosphorus content was 13.58 mg·l-1. Ammonia nitrogen removal rate increased to 97.88% after iron-zeolite crystal seed was added at a dose of 3.5g/150ml. Furthermore, cost analysis shows that using the bittern as magnesium precipitation agent has a certain advantage on cost.
- MAP /
- bittern /
- crystal seed /
- landfill leachate /
- pretreatment

[1]	赵庆良, 李湘中. 垃圾渗滤液中氨氮对微生物活性的抑制作用[J]. 环境污染与防治, 1998, 20(6):1-4
[2]	孙锦宜.含氮废水处理技术与应用[M]. 北京: 化学工业出版社,2003:93-96
[3]	童庆,王浩明,孙礼明.化学沉淀工艺去除高浓度氨氮反应机理及试验研究[J]. 环境科学与管理,2009,34(8):86-89
[4]	Izumi Hirasawa, Shogo Kaneko, Yuuji Kanai, et al. Crystallization phenomena of magnesium ammonium phosphate(MAP) in a fluidized-bedtype crystallizer[J]. Journal of Crystal Growth, 2002, 237:2183-2187
[5]	徐远,蒋京东,马三剑,等. 磷酸铵镁结晶沉淀法处理氨氮废水的应用研究[J]. 污染防治技术, 2006, 19(6):26-30
[6]	Sánchez E,Colmenarejo M F,Barrera J,et al. Kineticsof phosphorus removal and struvite formation by the utilization of by-product of magnesium oxide production[J]. Chemical Engineering Journal,2005,111:45-52
[7]	张乐观,刘彪.晶析辅助化学沉淀法处理高浓度氨氮废水的研究[J]. 平顶山工学院学报,2008,18(3):35-38
[8]	金亮, 李少华, 周勇,等.铁活化天然斜发沸石吸附水中氟[J].内蒙古石油化工,2009,13:18-19
[9]	Olcay Tunay, Isik Kabdasli, Derin Orhon, et al. Ammonia removal by magnesium ammonium phosphate precipitation in industrial wastewaters[J]. Wat Sci Tech, 1997,36 (2/3):225-228
[10]	WEF. Design of municipal wastewater treatment plants, Volume Ⅱ[M]. Alexandria, VA: Water Environment Federation and American Society of Civil Engineers, 1991:92-100

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商平, 刘涛利, 刘彦博. 苦卤-鸟粪石沉淀法预处理垃圾渗滤液[J]. 环境化学, 2010, 29(6): 1111-1115.

引用本文:

商平, 刘涛利, 刘彦博. 苦卤-鸟粪石沉淀法预处理垃圾渗滤液[J]. 环境化学, 2010, 29(6): 1111-1115.

SHANG Ping, LIU Taoli, LIU Yanbo. PRETREATMENT OF LANDFILL LEACHATE BY THE BITTERN- MAGNESIUM AMMONIUM PHOSPHATE PRECIPITATION METHOD[J]. Environmental Chemistry, 2010, 29(6): 1111-1115.

Citation:

SHANG Ping, LIU Taoli, LIU Yanbo. PRETREATMENT OF LANDFILL LEACHATE BY THE BITTERN- MAGNESIUM AMMONIUM PHOSPHATE PRECIPITATION METHOD[J]. Environmental Chemistry, 2010, 29(6): 1111-1115.

苦卤-鸟粪石沉淀法预处理垃圾渗滤液

1. 天津市海洋资源与化学重点实验室, 天津科技大学环境科学与工程系, 天津, 300457;
2. 天津泰达环保有限公司, 天津, 300222

收稿日期: 2009-12-26

基金项目:

天津市科技支撑计划重点项目(08ZCKFSH01600),天津市农业科技成果转化与推广项目(0802020)

关键词:

摘要: 以苦卤为新型镁沉淀剂,改性沸石为晶种,对鸟粪石沉淀法预处理高浓度氨氮垃圾渗滤液进行实验研究.结果表明:当n(Mg):n(N):n(P)=1.3:1.0:1.1,氨氮去除率为96.2%;铁沸石晶种在3.5g/150ml时氨氮的去除率增加到了97.88%.对新型镁沉淀剂成本分析表明,苦卤和改性沸石作鸟粪石沉淀剂和晶种是可行的.

English Abstract

PRETREATMENT OF LANDFILL LEACHATE BY THE BITTERN- MAGNESIUM AMMONIUM PHOSPHATE PRECIPITATION METHOD

1. Tianjin Key laboratory of Marine Resources & Chemistry, Department of Environmental Science and Engineering, Tianjin University of Science and Technology, Tianjin, 300457, China;
2. Tianjin Teda Environment Co., Ltd. Tianjin, 300222, China

Received Date: 2009-12-26

Fund Project:

Keywords:

Abstract: A new magnesium ammonium phosphate (MAP) method is described as a pretreatment for landfill leachates with highly concentrated ammonia nitrogen, with Na2HPO4 as phosphate ions and the bittern as a new substitute for magnesium precipitation agent. Within the time of 25 min, under the conditions of pH8.5, n(Mg2+):n(NH4+):n(PO43-) = 1.3:1:1.1, the removal rate of NH3-N at the stirring speed 250r·min-1can remain as high as 96.2%, while the residual phosphorus content was 13.58 mg·l-1. Ammonia nitrogen removal rate increased to 97.88% after iron-zeolite crystal seed was added at a dose of 3.5g/150ml. Furthermore, cost analysis shows that using the bittern as magnesium precipitation agent has a certain advantage on cost.

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苦卤-鸟粪石沉淀法预处理垃圾渗滤液

PRETREATMENT OF LANDFILL LEACHATE BY THE BITTERN- MAGNESIUM AMMONIUM PHOSPHATE PRECIPITATION METHOD

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苦卤-鸟粪石沉淀法预处理垃圾渗滤液

English Abstract

PRETREATMENT OF LANDFILL LEACHATE BY THE BITTERN- MAGNESIUM AMMONIUM PHOSPHATE PRECIPITATION METHOD

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